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578 of 291293; Italian Ministry of Health Decree n. 5 77) 51:49 75) 52:48 75) ()58: (--)42 75) -CO2CH(CH3)Bu t -CO2CH(CH3)Bu' -CO2CH(CHa)Bu' -CO2CH(CH3)Bu t -CO2CH(CH3)Bu t -(--)CO2-menthyl -(--)CO2-menthyl -(--)CO2-menthyl ( -(--)CO2-menthyl (--78 °C) -(--)CO2-menthyl -(--)CO2-menthyl -CCH3(OCHa)But -CO2CH(CH3)C6H5 -CO2CH2-2()-(P) [6] ( ( 80 25 °C) °C) 0 °C) The results, collected in Table 7 show an appreciable enantiomeric excess for l- substituted helicene, a lower excess for 5-s-abstituted helicenes and low selectivity in the formation of 2- 3- or 4-substituted products.

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